Preparation, Identification of Two New Cd(II) Complexes including 4-(1H-Tetrazol-5-yloxy) – Phenylamine Cadmium(II) Chloride and 2-(1H-Tetrazol) - Pyridine Cadmium(II) Chloride
نویسنده
چکیده
Two Cd complexes have been prepared by reaction of Cd (II) with 4-(1H-Tetrazol-5yloxy) – phenylamine (HTY) and 2-(1H-Tetrazol) pyridine (HTP) ligands. These new complexes were characterized by IR, UV-Visible, 1H-NMR and 13C-NMR spectroscopies. The changes observed between the FT-IR, H-NMR and UV-Vis spectra of the ligands and complexes allowed to establish the coordination mode of the metal in complexes.
منابع مشابه
catena-Poly[[bis(1-ethyl-1H-imidazole-κN 3)cadmium]-di-μ-chlorido-[(1-ethyl-1H-imidazole-κN 3)cadmium]-di-μ-chlorido-[(1-ethyl-1H-imidazole-κN 3)cadmium]-di-μ-chlorido-[bis(1-ethyl-1H-imidazole-κN 3)cadmium]]
The asymmetric unit of the crystal structure of the title compound, [Cd(2)Cl(4)(C(5)H(8)N(2))(3)](n), contains two Cd(II) cations, three 1-ethyl-1H-imidazole ligands, and four Cl(-) anions. The two Cd(II) atoms have quite different coordination environments: one is octa-hedrally coordinated by four Cl atoms and two N atoms from two 1-ethyl-1H-imidazole ligands, and the second is in a severely d...
متن کاملSynthesis of some novel triazole derivatives as anti-nociceptive and anti-inflammatory agents.
Eight novel 1-[2-(1H-tetrazol-5-yl)ethyl]-1H-benzo[d][1,2,3]triazoles (3a-h) have been synthesized in order to obtain new compounds with potential anti-nociceptive and anti-inflammatory activity. The titled compounds were synthesized by the condensation of 1-[2-(1H-tetrazol-5-yl) ethyl]-1H-benzotriazole (2) and appropriate acid chlorides. Compound 2 was synthesized by reacting 3-(1H-benzo[d][1,...
متن کاملAnti-tumor activity of Fe (III), Co(II) and Pd(II) complexes of N3-{phenyl [(4-pyridylcarbonyl)amino]methyl}
An anti-tumor compound as N3-{phenyl [(4-pyridylcarbonyl) amino] methyl} weresynthesized and identified (NPPA). Fe (III), Co(II) and Pd(II) metal complexes of this ligand preparedby reaction of chloride salt of Fe (III), Co(II) and Pd(II) with NPPA in dry acetonitrile. Identification andCharacterization of the ligand was performed by FT-IR, 1H-NMR spectroscopy and elemental an...
متن کاملSynthesis and Biological Evaluation 6-chloro-2-substitued-1-[2-(1h- Tetrazol-5-yl)-biphenyl-4-ylmethyl]-1h-benzoimidazol-5-ylamine Antihypertensive Agents
A series of methyl 6-Chloro-2-Substitued-1-[2-(1H-tetrazol-5-yl)-biphenyl-4-ylmethyl]1H-benzoimidazol-5-ylamine were successfully synthesized. Benzimidazoles were prepared by condensation of 4-chloro-o-phenylenediamine with substituted aryl, aldehyde condensation with biphenyl tetrazole group and reduction stannous chloride dihydrate. An insertion-cyclization strategy was involved during synthe...
متن کاملcatena-Poly[[bis[2-chloro-6-(1H-1,2,4-triazol-1-yl-κN 4)pyridine]cadmium(II)]-di-μ-thiocyanato-κ2 N:S;κ2 S:N]: a one-dimensional coordination polymer
In the crystal structure of the title complex, [Cd(NCS)(2)(C(7)H(5)ClN(4))(2)](n), the Cd(II) atom lies on a crystallographic inversion center and assumes a distorted octa-hedral geometry. The 2-chloro-6-(1H-1,2,4-triazol-1-yl)pyridine mol-ecule acts as a terminal ligand. The thio-cyanate ligands function as μ(1,3)-bridging units connecting adjacent Cd(II) atoms with a separation of 5.7525 (11)...
متن کامل